The thermal conductivity of solid SF6, CHCl3, C6H6, and CCl4 was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples. The contributions of the phonon-phonon and phonon-rotation interactions to the total thermal resistance were separated using the modified method of reduced coordinates. It is shown that the phonon-rotation contribution to the thermal resistance of the crystals decreases as the rotational motion of the molecules attains more freedom.

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