The spectrum of thermally stimulated depolarization currents, dielectric losses, thermally stimulated luminescence, IR transmission and absorption spectra and NMR-spectra of protons in widezone hydrogenbonded crystals had been investigated. The lines caused by protons and proton defects hesitations had been discovered in IR-spectra. In the NMR spectra revealed peaks corresponding to two non-equivalent protons. The influence of transport and tunneling of protons on the spectra of the investigated parameters is discussed. There is considered the quantum-mechanical approach to the tunneling of protons where the transparence of barrier and de Broglie wavelength had been determined.

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