This work relates to the study of vibrational structures in the electron spectra of naphthalene crystals with impurities of <$E beta>- and <$E alpha>-naphthalene fluorine with concentrations of 10<^>-4 to 10 wt.% at a temperature at 4,2 K. It is determined that, at low impurity concentrations, the spectra have a doublet structure and consist of narrow quasilines with initial values of v01 = 31 322 cm<^>-1 and v02 = 31 226 cm<^>-1, which are resonance-coincident in the absorption and fluorescence spectra. It is demonstrated that if the impurity concentration increases, the series of narrow quasilines appear in the areas of the 0-0 transitions of the impurity centers of both types together with the doublet structure. A part of these quasilines is polarized predominantly along the b-axis of a naphthalene crystal. The model is proposed for impurity centers, which induce the generation of new spectral bands. This model is based on the interaction of translation-nonequivalent impurity molecules in the elementary lattice cell of a naphthalene crystal. At high impurity concentrations, the resonance-symmetric wide spectral bands appear in the absorption and fluorescence spectra. The analysis of the results obtained is performed with consideration for the Franck - Condon interaction and the Herzberg - Teller interaction.

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